Investigation of double electron capture in 106Cd was performed at the Modane underground laboratory (4800 m.w.e.) using the multi-detector spectrometer TGV-2. In Phase I of the experiment, ∼10 g of 106Cd
with an enrichment of 75% was measured during 8687 hours. In Phase II, the TGV-2 background was significantly suppressed in comparison with Phase I and the 106Cd mass was increased to ∼13.6 g. New half-life limits (at 90% CL) were obtained for 2νEC/EC decay of 106Cd to the ground state of 106Pd – T1/2 > 3.0 × 10^20 y (Phase I) and T1/2 > 3.6 × 10^20 y (Phase II, 9000 hours), and for 0νEC/EC decay of 106Cd to the 2741 keV excited state of 106Pd – T1/2 > 1.1×10^20 y (Phase II).